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Heyrovsky Institute Community"}, "access": {"visibility": "public", "members_visibility": "public", "member_policy": "closed", "record_submission_policy": "open", "review_policy": "closed"}, "custom_fields": {"workflow": "community", "allowed_workflows": ["community"]}, "deletion_status": {"is_deleted": false, "status": "P"}, "children": {"allow": false}}]}, "pids": {"doi": {"identifier": "10.48700/xptxx-crs22", "provider": "datacite", "client": "datacite"}}, "workflow": "community"}, "versions": {"is_latest": true, "index": 1}, "is_published": true, "is_draft": false, "pids": {"doi": {"identifier": "10.48700/datst.hwbrn-ed377", "provider": "datacite", "client": "datacite"}, "oai": {"identifier": "oai:datarepo.eosc.cz:datst.hwbrn-ed377", "provider": "oai"}}, "metadata": {"publication_date": "2025-04-16", "title": "Data for Structural and Chemical Changes in Si Nanoparticle-Based Anodes in Lithium-Ion Batteries during the (De)lithiation Processes Studied by In Situ Raman Spectroelectrochemistry", "publisher": "Fyzik\u00e1ln\u00ed \u00fastav AV \u010cR", "additional_descriptions": [{"description": "<b>This dataset supports the published article titled \"Structural and Chemical Changes in Si Nanoparticle-Based Anodes in Lithium-Ion Batteries during the (De)lithiation Processes Studied by In Situ Raman Spectroelectrochemistry.\" It contains in situ Raman spectroelectrochemical data, as well as data from cyclic voltammetry and galvanostatic charge/discharge measurements of silicon anodes prepared from 6 nm Si nanoparticles.</b><span>&nbsp;The in situ Raman SEC provides unique insight into the crystal lattice changes and degradation/amorphization pathways of the Si nanocrystals and the electrolyte (LiPF</span><span>6</span><span>&nbsp;in EC/DMC) decomposition during the electrochemical lithiation and delithiation processes. 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The structural changes in the anodes determined using in situ Raman SEC show good agreement with the results obtained from cyclic voltammetry measurements, revealing a progressive crystalline-to-amorphous Si phase transition and a complex energy storage mechanism in nanostructured silicon anodes in LIBs.</span>", "type": {"id": "abstract", "title": {"cs": "Abstrakt", "en": "Abstract"}}, "lang": {"id": "eng", "title": {"cs": "angli\u010dtina", "en": "English"}}}, {"description": "<span>TEM,&nbsp;</span><span>Raman spectroscopy, cyclic voltammetry, galvanostatic charge/discharge, in situ Raman spectroelectrochemistry</span>", "type": {"id": "methods", "title": {"cs": "Metodologie", "en": "Methods"}}, "lang": {"id": "eng", "title": {"cs": "angli\u010dtina", "en": "English"}}}, {"description": "<span>See the experimental part in&nbsp;</span><span>https://pubs.acs.org/doi/full/10.1021/acsaem.5c00066.</span>", "type": {"id": "technical-info", "title": {"cs": "Technick\u00e1 informace", "en": "Technical Info"}}, "lang": {"id": "eng", "title": {"cs": "angli\u010dtina", "en": "English"}}}], "creators": [{"person_or_org": {"type": "personal", "name": "Vl\u010dkov\u00e1, Zuzana", "given_name": "Zuzana", "family_name": "Vl\u010dkov\u00e1", "identifiers": [{"identifier": "0000-0001-9441-0577", "scheme": "orcid"}]}, "affiliations": [{"id": "02sat5y74", "name": "Czech Academy of Sciences, Heyrovsky Institute", "identifiers": [{"identifier": "02sat5y74", "scheme": "ror"}, {"identifier": "grid.425073.7", "scheme": "grid"}, {"identifier": "0000 0004 0633 9822", "scheme": "isni"}]}]}, {"person_or_org": {"type": "personal", "name": "Sonia, Farjana J.", "given_name": "Farjana J.", "family_name": "Sonia", "identifiers": [{"identifier": "0000-0002-9671-909X", "scheme": "orcid"}]}, "affiliations": [{"id": "02sat5y74", "name": "Czech Academy of Sciences, Heyrovsky Institute", "identifiers": [{"identifier": "02sat5y74", "scheme": "ror"}, {"identifier": "grid.425073.7", "scheme": "grid"}, {"identifier": "0000 0004 0633 9822", "scheme": "isni"}]}]}, {"person_or_org": {"type": "personal", "name": "Jindra, Martin", "given_name": "Martin", "family_name": "Jindra", "identifiers": [{"identifier": "0000-0002-3396-8830", "scheme": "orcid"}]}, "affiliations": [{"id": "02sat5y74", "name": "Czech Academy of Sciences, Heyrovsky Institute", "identifiers": [{"identifier": "02sat5y74", "scheme": "ror"}, {"identifier": "grid.425073.7", "scheme": "grid"}, {"identifier": "0000 0004 0633 9822", "scheme": "isni"}]}, {"id": "05ggn0a85", "name": "University of Chemistry and Technology, Prague", "identifiers": [{"identifier": "05ggn0a85", "scheme": "ror"}, {"identifier": "grid.448072.d", "scheme": "grid"}, {"identifier": "0000 0004 0635 6059", "scheme": "isni"}]}]}, {"person_or_org": {"type": "personal", "name": "M\u00fcller, Martin", "given_name": "Martin", "family_name": "M\u00fcller", "identifiers": [{"identifier": "0000-0001-7958-1634", "scheme": "orcid"}]}, "affiliations": [{"id": "02yhj4v17", "name": "FZU \u2012 Institute of Physics of the Academy of Sciences of the Czech Republic", "identifiers": [{"identifier": "02yhj4v17", "scheme": "ror"}, {"identifier": "grid.424881.3", "scheme": "grid"}, {"identifier": "0000 0001 2167 976X", "scheme": "isni"}]}]}, {"person_or_org": {"type": "personal", "name": "\u010cervenka, Ji\u0159\u00ed", "given_name": "Ji\u0159\u00ed", "family_name": "\u010cervenka", "identifiers": [{"identifier": "0000-0002-1873-2475", "scheme": "orcid"}]}, "affiliations": [{"id": "02yhj4v17", "name": "FZU \u2012 Institute of Physics of the Academy of Sciences of the Czech Republic", "identifiers": [{"identifier": "02yhj4v17", "scheme": "ror"}, {"identifier": "grid.424881.3", "scheme": "grid"}, {"identifier": "0000 0001 2167 976X", "scheme": "isni"}]}]}, {"person_or_org": {"type": "personal", "name": "Fejfar, Anton\u00edn", "given_name": "Anton\u00edn", "family_name": "Fejfar", "identifiers": [{"identifier": "0000-0003-0988-0772", "scheme": "orcid"}]}, "affiliations": [{"id": "02yhj4v17", "name": "FZU \u2012 Institute of Physics of the Academy of Sciences of the Czech Republic", "identifiers": [{"identifier": "02yhj4v17", "scheme": "ror"}, {"identifier": "grid.424881.3", "scheme": "grid"}, {"identifier": "0000 0001 2167 976X", "scheme": "isni"}]}]}, {"person_or_org": {"type": "personal", "name": "Frank, Otakar", "given_name": "Otakar", "family_name": "Frank", "identifiers": [{"identifier": "0000-0002-9661-6250", "scheme": "orcid"}]}, "affiliations": [{"id": "02sat5y74", "name": "Czech Academy of Sciences, Heyrovsky Institute", "identifiers": [{"identifier": "02sat5y74", "scheme": "ror"}, {"identifier": "grid.425073.7", "scheme": "grid"}, {"identifier": "0000 0004 0633 9822", "scheme": "isni"}]}]}], "dates": [{"date": "2025-04-16", "type": {"id": "available", "title": {"cs": "Datum zve\u0159ejn\u011bn\u00ed", "en": "Date Available"}}, "description": "The date the resource is made publicly available. 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